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Difference between revisions of "Conformational nomenclature"
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==References== | ==References== | ||
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| − | # | + | #IUPACNomenclature1981 Conformational nomenclature for five- and six-membered ring forms of monosaccharides and their derivatives, Pure and Appl. Chem., 1981, ''53'', 1901—1905. [http://dx.doi.org/10.1351/pac198153101901 DOI: 10.1351/pac198153101901] |
#Stoddart1971 Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages. | #Stoddart1971 Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages. | ||
</biblio> | </biblio> | ||
[[Category:Definitions and explanations]] | [[Category:Definitions and explanations]] | ||
Revision as of 07:20, 4 August 2013
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The conformations adopted by a pyranose or furanose ring are denoted by a system in which a capital letter indicates the overall shape, C = chair, B = boat, H = half chair, S = skew boat, E = envelope [1]. The first four of these conformations has four atoms in a plane; the envelope conformation has five.
The particular conformation is then denoted by assigning the letter corresponding to the shape (C, B, H, S, E); determining the four (or five) atoms that define the plane; assigning a 'top' and 'bottom' face through the use of a left-hand rule counting in the order of increasing ring carbon; and then indicating the identities and relative positions (top face = superscript and prefix; bottom face = subscript and suffix) of the remaining two atoms on that capital letter. In the case of the envelope conformation, only a single atom is located outside of the plane. For a more detailed discussion see the excellent book by J. Fraser Stoddard [2].
References
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Stereochemistry of Carbohydrates, J. Fraser Stoddart, John Wiley & Sons Inc, 1971, 264 pages.
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Conformational nomenclature for five- and six-membered ring forms of monosaccharides and their derivatives, Pure and Appl. Chem., 1981, 53, 1901—1905. DOI: 10.1351/pac198153101901