CAZypedia needs your help!
We have many unassigned pages in need of Authors and Responsible Curators. See a page that's out-of-date and just needs a touch-up? - You are also welcome to become a CAZypedian. Here's how.
Scientists at all career stages, including students, are welcome to contribute.
Learn more about CAZypedia's misson here and in this article.
Totally new to the CAZy classification? Read this first.
Oxazolinium ion
This page has been approved by the Responsible Curator as essentially complete. CAZypedia is a living document, so further improvement of this page is still possible. If you would like to suggest an addition or correction, please contact the page's Responsible Curator directly by e-mail.
- Author: Spencer Williams
- Responsible Curator: Spencer Williams
An oxazolinium ion is the species that is formed by anchimeric assistence in the glycosidic bond-cleaving reaction of a 2-deoxy-2-acetamido glycoside [1]. An oxazolinium ion can be deprotonated to give an oxazoline, which is a stable and isolable species. Oxazolinium ions are common intermediates in the neighboring group participation mechanism of glycoside hydrolases, including glycoside hydrolases from families GH18, GH20, GH25, GH56, GH84, and GH85.
See also
References
-
Tews, I., Terwisscha van Scheltinga, A.C., Perrakis, A., Wilson, K.S., and Dijkstra, B.W. J. Am. Chem. Soc. 1997, 119, 7954-7959.